I wanted to loop through each of the Content values in $Records.Content, but i cant seem to find a way to do this, since the Content section, is an string - or am i wrong?
Without getting into the API, if you have a string you want to split into an array so you can do things like iterate over, look at the -split operator. It will turn a string into an array of strings based on a regular expression (delimiter to split on) or any white space (when used as unary operator). See get-help about_split.
As Fer was saying, Invoke-RestMethod will convert the JSON into a PSObject, which can be parsed. It appears Content-Type is a semi-colon delimited string, so as Mike said you can use split to turn that into an array.